The Pokemon appear on any day so be surprised when you randomly find it.
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trophy garden x
i got a mime jr. at the trophy garden but they are rare, you can evolve mime jr. by knowing mimic.
There is no mime jr. on Pokemon pearl. On diamond there is mime jr. on Pokemon pearl there is bonsly
You could grab a Mr. Mime on Route 218 and then attach an Odd Incense to it and breed it with another Pokémon in order to hatch a Mime Jr. or you could find one at the Trophy Garden behind the Pokémon Mansion however using the Trophy Garden is very hard to do cause Mime Jr. is one of its many Pokémon that changes daily meaning you first have to check with Mr. Backlot to see if it's in the Trophy Garden or not.
The Trophy Garden is behind the Pokemon Mansion in Sinnoh. Several Pokemon can only be found there. Pokemon able to be caught in the garden include: Pichu, Pikachu, Staravia, Roselia, and Kricketune. Afer talking to Mr. Backlot, special Pokemon appear in the garden including: Clefairy, Jigglypuff, Meowth, Chansey, Ditto, Eevee, Porygon, Cleffa, Igglybuff, Marrill, Azurill, Plusle, Minun, Castform, Bonsly, Mime Jr., and Happiny.