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Press A and B repeatidly
It is said that with a great ball, when the ball "hits" the invisible wall before dropping on the poke'mon, you press and hold down the L and R buttons simultaneously as soon as it "hits the wall."
Then, the moment it hits the ground you hold down B as well. This is supposed to give the great ball a 85% chance of catching the poke'mon, better then an ultimate ball, but worse then a master ball. Even if this doesn't actually work, I seem to have a fairly high success rate.
(I also do the same thing with ordinary poke'balls, but it doesn't seem to work)
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