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Find them on a certain day, time, and place and you will get their phone numbers. Then, on another certain day/time/place you can call them for a rematch.
Right next to the Saffron city gym. You can use it to battle gym leaders you have already defeated if you have their phone number and phone them when they are not busy. You may not be able to get all of the phone numbers, before you battle Red, and they might all have 6 Pokemon apiece in the fighting dojo battles.
You need to get their Phone Numbers, by taking a picture with them at certain times of the week, and time zone. there is also a place where they will go after you get said phone number reference youtube for dates/times for the rematchs.
You cannot get Lance's number in Pokémon HeartGold since he is the Pokémon League Champion you can only get numbers from trainers that are not in caves or mountains and you can also get numbers of any of the 8 Gym Leaders in the Johto region or any of the 8 Gym Leaders in the Kanto region.
on thurs afternoons go to viridian forset and look for him