Any one you want to train or breed.
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You put Empoleon and Ditto to the Pokemon Day Care and wait for a long time. Then go back to Pokemon Day Care talk to the old man.
Put 2 pikachu in the day care
If you do that the pokemon will have a egg.
Put a male and female Pokemon( must be same Pokemon) in the day care together. Or put a ditto and the Pokemon you want to breed in the daycare.
Although it costs quite a bit to put your Pokemon in the Day Care Center, it is very helpful. Firstly, the Pokemon's level is raised whilst it is in, and secondly, if you put two in of the same species but of different genders, you may also get an egg.