Focus Punch is most powerful, but is un-reliable with using substitute first, considering if the opponent hits you it fails. Brick Break is most reliable.
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you should choose torchic because fire and fighting is good at most hoenn gyms
I would say that fire is the most effective. Jynx is a Ice and Psychic type. Fire, Fighting, Rock, Steel, Bug, Ghost, and Dark will Be the most effective.
Lucario- Fighting and Steel type. Lucario can learn moves of every type except for Grass and Flying type moves. However, Lucario's most powerful moves are Fighting Type so it is good to use Flying, Ghost, Poison, Psychic or Bug Types. As for what moves you should use, Fire, Fighting and Ground Type moves are all super effective.
first you pass the first five gyms then you either get your best fire type Pokemon or fighting or ground they are the most effective against steel type Pokemon then you pass it.
The most powerful water type is Suicune.