In Ruby and Sapphire Routes 102, 114, 117, 120. But there VERY RARE! 1% chance of finding them.
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No Surskit's evolution is Masquerain.
Surskit evolves into Masquerain at Level 22.
You actually find surskit in the grass not in water.
Masquerain
No, Surskit is one of the only Water Pokemon (along with Wingull and Magikarp) who cannot learn Surf.