theres a guy who gives you 5 of them if you show him a certain pokemon. hes thenews reporter guy in solaceon town. they dont start selling them until after the 7th or 8th badge.
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Luxury balls are a type of Poke ball for the game Pokemon. They are hard to find, so are worth more than other types of balls.
Give a Pokemon in Pokemon Emerald, Sapphire, or Ruby a luxury ball to hold and trade to Fire Red. You can get extra luxury balls by winning a master rank contest after your Pokemon already has the ribbon. There is also one luxury ball in the abandoned ship, but you need dive. As far as I know, you cant get the luxery bal without tradeing with the other games I listed, or trade with someone who already has luxury balls. -BubbaJ
You can buy them at the Pokemon mart at the Pokemon league. I buy my timer balls, heal balls, etc. at the Pokemon mart in canalave city
Hearthrome city
You don't need the boat ticket in Pokemon Platinum because it's the ticket for Luxury Liner SS Anne, which is not in the Sinnoh region.