Go to Hearthome city. To the right of the Pokemon centre, there is a house. Go to that house, making sure you have an empty slot in your battle team. Talk to the person inside the house, and he/she will give you an Eevee.
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to get a leafeon in Pokemon platinum, you need to have an eevee and then at any lvl you have to use a leaf stone!
a lady in a house next to the Pokemon center will give you an eevee
The trainer Skier Lexi on Route 217 has Eevee's evolution in Pokemon Platinum. The trainers on Route 212 and 214 also have Eevee.
sinnoh pokedex: #163 is eevee. you can find eevee in Mr.Backlot's garden. (depending on the Pokemon of the day) National dex: #133 is octillery. i don't know where to find it. Sorry!