In twist mountain.
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Trade star pieces for shars at Fuego Ironworks. Find star pieces underground.
You cannot buy them but im sure you can trade star pieces for PP-ups to a guy in Anville town on weekends
zoroa is a new legendary Pokemon unique to Pokemon black and white (its moves type and any other specific information about this Pokemon have not been revealed yet) It will star in the 13th Pokemon movie although I forget the title.
you get them from underground, random spots, or you can trade star pieces for a set of 1 shard of each color.
Pokemon diamond