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Use action replay.
you cannot clone rare candies in sapphire. you can use Action replay to get more however
In order to receive unlimited rare candy in Pokemon Blue, first travel to Viridian City. Walk over to the northwest corner of the city and continue north. At this point, place a piece of rare candy as the sixth item on your list and talk to the bald man on the path. When he asks you if you are in a hurry, reply with "no." After listening to his speech, fly to Cinnabar Island and walk to the western coast of the island. Surf along the coast until you find a wild Missingno. Run away from the Missigno (do not attempt to capture) and you will receive unlimited rare candies.
Yes there is rare candy in pearl
you find rare candy in the random pokeballs