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On Route 123
go around mt. pyre from route 121 when you get to the other side your on route 123
In Sapphire and Emerald, you can find Seviper at Route 114. In Diamond, Pearl, and Platinum, Route 208(Sapphire has to be in the GBA slot.).
Route 114 is West of Fallarbor Town.
Route 102 on Pokemon Sapphire.