1- Pewter city's BROCK 2- Cerulean city's MISTY 3- Vermilion city's LT.SURGE 4- Celadon city's ERIKA 5- Fuchsia city's KOGA 6- Saffron city's SABRINA 7- Cinnabar Island's BLAINE 8- Viridian city's GIOVANNI 9-12- Pokemon League's ELITE 4 13- Pokemon League's CHAMPION
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The 8 Gyms in Leaf Green are in Pewter City, Cerulean City, Vermilion City, Celadon City, Saffron City, Fuchsia City, on Cinnibar Island and in Viridian City.
Go to Indigo Plateu. You will battle Elite Four there and that is the end of the game. Dont worry, you will still be able to continue with game after you beat them. Train your Pokemon before going to Elite Four because they are strong.
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Pokemon HeartGold, SouldSilver