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That's the one left of Oldale town, right? Seedot (rare), Lotad, Zigzagoon, Poochyena, and Ralts (rare). Get a Ralts, they're fantastic.
I found zigzagoon in the pokewalker on hoenn fields.
Yes, Zigzagoon is able to learn Surf.
No Pokemon can make rare candies, but some Pokemon have the Pickup ability which give them a chance of picking up items randomly including rare candies. Some of these Pokemon include Zigzagoon, Linoone, Meowth, and Sentret.
zigzagoon evolves at level 20