your rival has one. if you battled him everytime then battle him in the fight area. if you want to use that catching people Pokemon cheatr then you can also catch a grotle from some person in route 210.
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Cynthia the Pokemon Champion has a Milotic in Pokemon Diamond, Pokemon Pearl and Pokemon Platinum.
There actually isnt a trainer in pokemon pearl that has drifloon, but you can catch them every friday in front of the valley windworks, just go up to the drifloon and press a. he is at level15
No trainer have Rotom in Pokemon Pearl, Diamond, or Platinum.
pokemon breeder in route 210 he has pichu, happiny,pikachu