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Steam is a gaming community where people purchase and play multi-player games online. A key is what a user enters to access beta features. (Features that are still in testing)
Yes you can, you import and add non-steam games to your Steam library. From within the library you can launch and run any games, although 'Steam achievements' will only be available for Steam enabled games.
Yes, some. Not all of them can be activated on Steam. See the related links for a list of the games that can be activated on Steam and for the instructions on how to activate a game on Steam.
You can't.
No, but there is a steam function to add non steam games on to your library.