It can't be found in Pokemon Gold or Silver. Only in Crystal, where can teach your Pokemon Flamethrower by finding the Move Tutor outside Mt. Silver on Saturdays and Wednesdays after you have defeated the Elite Four. It can be found in Heartgold and Soul Silver as well.
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Tm. 35
There's no tm for it. Pokemon can only learn it.
You can get TM 25 (Flamethrower) at the Mauville Game Corner for 4000 coins.
TM35
TM35.