Palkia can learn flamethrower with a TM otherwise NO
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catch or defeat palkia and go to lake valor and you Will find azelf
machop is a good hm slave. he can learn rock smash, rock climb, strengh,. in Pokemon emerald nincada is a good hm slave but in Pokemon pearl flash is not an hm. any water type can learn waterfal or surf espacially palkia.
fire type is weak against palkia it is a water and dragon type Pokemon
Okay you can find a TM for the move flamethrower in a place called fuego fire works, which is located Right near Floaroma Town and Route 204 also if you have a fire type pokemon as he/she levels up they will learn the move flamethrower (the level a pokemon learns flamethrower are all at different levels for each fire pokemon).ENJOY!.Posted By:Pokemon Info at www.facebook.com.auIf you would like any more info check out our page!
after u beat the elite four