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There is no cheat in Pokemon to get additional PC boxes. Those who need additional space in Pokemon X and Y can use Nintendo's Pokemon Bank service.
if u use any masterball cheat u get bad egg in Pokemon PC
press a on PC, go to storage, then withdraw. your Pokemon should be there.if not, try to look through the categorys.
You can't unlock storage wallpapers.
as far as i know without a cheat you cant but heres the cheat 82025840 0154 Its in your PC