he is in a Pokemart
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in any pokemart near the counter.
In Pokemon Diamond Pearl and Platinum, a man in a green suit can be found in the Pokemarts. He is not in any specific city. He is just in every Pokemart.
in the pokemart after you use mystery gift.
You need to be more specific. LUCKILY, I know what your reffering to. You are talking about the arceous event in diamond/pearl/platinum. He will be in any pokemart in a green suit. After you have activated the event.
A guy in a green suit will only appear in a Pokemart if you have participated in a Pokemon event. For a list of events, click the link below. (In "related links")