Nope. But he is really cool. Every ten levels he learns sketch which then can be used to teach him literally any move.
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You catch Smeargle ;)
You can find Smeargle in route 212 using the Poke Radar.
Smeargle is a Normal type Pokemon known especially for its unique move Sketch. It cannot be caught anywhere in the wild in Pokemon FireRed and must be traded over from another game.
you can catch sudowoodo and smeargle
you find him in the ruins of alph by weeds and you can find smeargle on there same thing on Pokemon heart gold (natu evolves at level 25)(smeargle no evolvetion)