It's not in the main series. It's in the movie "Bojack Unbound."
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Gohan Fought Bojack in the 9th Movie of DBZ and Killed Bojack By using the Super Saiyan 2.
episode 176
Gohan goes mystic in Episode 247: Unlucky Break
They actually met in high school in the episode '' Gohan goes to high school ''
episode 166