He turns into super saiyan 4 on episode 59 when he fights omega shenron.
Of series gt.
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Episode 214: Vegeta's Pride. Goku turns to USSJ (Ultra Super Saiyan) and USSJ2 in the Hyperbolic Time Chamber. He turns to SSJ2 while fighting Majin Vegeta.
Episode 230 "Super Saiyan 3"
Episode 207, "Take Flight Videl", while at 150x gravity and vegeta punches him in the face. Hahahaa
Super Vegito is the fusion of Goku & Vegeta when they turn Super Saiyan and then they merged together by wearing the Potara Earrings
gohan turns super saiyan 2 in episode number #170 It's actually DBZ Episode 185-Awakening