Well, episodes are usually numered from 1. Watch in that order, 1 then 2 then 3. Search for "season 1" then "season 2" then "season 3" and so on.
Same for the movies.
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You can watch Pokemon videos (episodes) on pokemon.com. It is the official Pokemon website. You can watch FREE Pokemon episodes and do all sorts of Pokemon related activities.
You can watch new Pokemon episodes on Cartoon Network every Saturday and Sunday in the mornings.
A great website for watching Pokemon episodes online is www.pokemonepisode.orgIt has every episode from Season 1, and even all the movies! You can try animefreak.tv too, it has all anime that i know of
I have watched some pokemon episodes and movies on livevideo.com and it seems safe. I haven't had any viruses or any other problems on my computer since watching the pokemon episodes and movies so I think it is safe to use. Don't go on it if you still have doubts, but it seems safe to me. Hope this helped.
www.pisoga.com had all sorts of anime which has all of the first 519 Pokemon episodes and all 10 movies, but they are in megavideo =\. they have a great list of anime from A - Z