A great website for watching Pokemon episodes online is www.pokemonepisode.orgIt has every episode from Season 1, and even all the movies! You can try animefreak.tv too, it has all anime that i know of
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You can watch full length Pokemon episode on Cartoonnetwork.com or Pokemon.com/us
go to www.pokemonash.weebly.com
There are some episodes that claim you can watch the first episode of Pokemon online. Watch Pokemon Episodes, Anime Freak, Anime Crazy are just a few. The show is also probably available for Netflix and Hulu Plus subscribers.
You can watch Pokemon videos (episodes) on pokemon.com. It is the official Pokemon website. You can watch FREE Pokemon episodes and do all sorts of Pokemon related activities.