May battles Dawn in episode 544, "Strategy with a Smile" for the Wallace Cup.*Update* The Correct Episode of the entire TV show is Episode 545.
The best way to find it is by season and by episode of that season (not the episode of the entire tv show)
There are four series of Diamond and Pearl. This Episode follows underPokémon Diamond & Pearl: Battle Dimension, which is the eleventh season of Pokemon and the Episode of that season is 79 or DP079. Is dubbed from Japan asDecisiveMatch! Hikari (Dawn) VS Haruka (May) and in America it is calledStrategy with a Smile!
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Dawn meets May in Episode 544 which is titled "A Full Course Tag Battle" which is part of the Diamond and Pearl Battle Dimension season.
Dawn doesn't meet May in an episode during the Galactic Battles season, she meets her in a Pokémon episode titled "Our Cup Runneth Over" which is during the "Battle Dimension" season.
episode 544- Stragety With a Smile! Season 11they met in a full course tag battle( episode DP076)
It is Episode 22 in Pokemon Battle Dimension what i did not see that show my pic then so i no that may down are tied up gagged
The names of the episodes are: Pruning A Passel Of Pals, Strategy with a Smile, Staging A Heroes Welcome, and A Full Course Tag Battle.