I believe it is normally 8 AM but I could be wrong.
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You can't.
u've either accidently put a cheat in (as making adults go to school has multiple cheats) or they aren't actually adults!
You get the parent or the child if they are a teenager or you get the students to walk to school, which you can only do (I think) if you have the Apartment Life expansion pack for the normal Sims 2 game, not the stories one.
To keep your kid in school in the Sims 1 or 2 or 3 you have to make sure they are up and that they catch the bus. As long as they don't skip school they should be fine. It really is easy:)
Well, you either get the parents (or the child if they are a teenager) to drive the kids to school or get them to walk, which I think you can only do if you have Apartment Life.