u dawn or ur rival whichever u choose
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If you chose Chimchar as your starter, your rival will eventually get a Prinplup. Also, at the Pokémon mansion, one trainer will have a Prinplup.
The only way to get chimchar piplup or turtwig is at the trading center in Jublife CityBut to get them on your Pokedex turtwig- second gymchimchar-trainer on rout 207piplup-trainer on route 205
You can get a Chimchar if you trade it from games Diamond, Pearl, and Platinum.
in the begining of the game the profeser will give you three Pokemon and you have to pick one the three Pokemon are chimchar,piplup and turtwig.
Poketransfer from Pearl Diamond or Platinum