James is 21 years old Ash is 10 Misty is 10 and maybe about to turn 11 brock is 15 jessie might be 20 or maybe 22 and gary is 10 ritchie is 10 and meowth's age is unknown so no more questions :)
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they are both 17, according to the Pokemon wiki
They are not in Pokemon HeartGold
There is not evidence that James from Pokemon is gay. If someone were gay, the reason why would be that they were born that way.
In "Pokemon Shipwreck" James admitted he liked Jessie, but she seemed to have more important things to do then have a crush on James. In the manga, Jessie and James are married and Jessie is pregnant.
Sweet Baby James