It starts off with 10 PP but you can always raise it with PP Up
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You can get the Sludge Bomb TM in Route 43 or you can buy Sludge Bomb at the Battle Frontier.
Sludge bomb: team rocket HQ (island 5)
You find the sludge bomb, team rocket HQ on island 5.
Yes all poison moves are physical attacks which means the more attack a Pokemon has the more it will hurt. Though if your facing a pikachu with static and you use sludge bomb on it you will NOT be affected by static.
on island 5 in the rocket ware house