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Pokemon Sapphire is a GBA game - since a DSi does not have the GBA slot unlike the regular DS or the lite, it cannot play Pokemon Sapphire.
As far as the game goes, you can't duplicate Pokemon on Sapphire. Tried it and it glitched up.
Pokemon Emerald,Ruby and Sapphire
Need a metal coat and trade like a golem I like Pokemon so much that i almost played every Pokemon game
You can't catch it in Pokemon Sapphire, Ruby, Emerald. The only way to obtain it is to buy it in the Game Corner for 9999 slot coins in Pokemon FireRed and LeafGreen and then trade it to your Ruby/Sapphire/Emerald game.