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In normal game-play, you can only get one Master Ball in the game, given to you by the president of Silph Co. after defeating Giovanni in the Silph Co. building at Saffron City. It is also possible to trade Master Balls from another game, by letting the Master Ball from the other game be held by a pokemon and trading it to your game. Without this trading method, however, you are only given one Master Ball to use.

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Q: How many masterballs do you get in Pokemon LeafGreen?
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