he cant learn it
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At Level 45 a Gligar or Gliscor will learn Guillotine
A TM for Cross Poison doesn't exist. Look here to learn which pokémon can learn it by level up: http://bulbapedia.bulbagarden.net/wiki/Cross_Poison
use arerrial aice with staraptor when it's at lv.70
No. for some odd reason it cant.
You must level up Parasect, Crobat, Skorupi or Drapion to have a Pokemon that knows Cross Poison. It is not a TM.