you shoot them
sniper404
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use the cheat code and buy them in the mart 958D8046A7151D708BB602F78CEB681A
Buy a Action replay and stuff
http://GSHI.org is the best place to look for GameShark, Action Replay, CodeBreaker, Game Genie, and other cheat device codes. Anyway, here are a few... Rare Candy is 82025840 0044. Walk Through Walls is 509197D3542975F4 78DA95DF44018CB4. Master ball is 82003884 0001. And to go with the Master ball cheat so you can buy 99 at a time and this is it. Everything in mart is $1 is 3C25A344FD8F451C, AD86124F2823D8DA.
Add "01017CCF" to the emulator's Gameshark cheat list. You can now buy 99 Master Balls for free in any mart.
You can buy them, at the Pokemon leuge thjey have evry kind of ball except master and cherish balls