You mean totodile right?
In Ilex Forest there is a guy who can learn you the move headbutt.
(Be carefull, once a Pokemon learned headbutt they can't forget it anymore.)
Hope it helped! :)
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Headbutt is no a HM in Pokemon soulsilver. However a man in Ilex Forest will teach it to any Pokemon that can learn it.
Headbutt dosn't come in a TM. You can teach a pokemon Headbutt by talking to a guy in a pink shirt in the Illex Forest. You can Headbutt trees (Like an HM) to find certain PoKeMoN.(It vairies where you Headbutt.)
headbutt trees
headbutt trees
In ilexforest there are guy who teach headbutt for your pokemons