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You must first reach the top of the lighthouse. Once at the top, you will have to give her the Secret Medicine. Here's a short guide.

GUIDE:

Step 1. Cross Routes 40 and 41 to get to Cianwood City. In here, get the Secret Medicine from the Cianwood Pharmacy.

Step 2. Head back to Olivine City and climb the lighthouse. Battle all of the trainers (if you have done this, then take the elevator up).

Step 3. Give Jasmine the Secret Medicine and it will heal the pokemon.

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Q: How do you talk to Jasmine in Pokemon SoulSilver?
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