While choosing your hair, there should be a padlock icon at the top-right. If it's locked, then your chosen hair will be set for all clothing. If you click on that, it should unlock, so you can individually set hairstyles for different outfits. You have to go back and forth the clothing section and the hairstyle section if you want to set hairstyles individually, though.
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you can get a mirror and that will change your sims hair and makeup. to change their everyday,formal,swimwear, and sleepwear you can click the dresser and it will give you the option to "plan outfit" which canges your sims clothes.
well when i was playing sims 3, i made my sim become a maid and then they unlocked the maid outfit and hair. [it works for most careers] but if you cant be bothered doing that, there is a cheat. cheat: unlockoutfits on that cheat unlocks all hair and outfits
You can get new maternity clothes for Sims 2 by downloading Squinges mod; pregnant Sims wear any outfit.
You must have the sims launch open, and the hair/whatever, must be installed on to the sims. Also, you must be logged on in your launcher!
go on cheats world click on s ans the sims 2 will come up.