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At the time of writing this answer, Darmanitan is only avaliable in Pokemon Black & White (including Black II & White II). You can obtain darmanitan after completing the main story by going to the desert resort and speaking to Professor Juniper, who gives you a RageCandyBar. This allows you to wake up one of the Darmanitans. However, it's probably easier to evolve one from Duramaka. It evolves at level 35.

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Q: How do you obtain darmanitan?
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