At the time of writing this answer, Darmanitan is only avaliable in Pokemon Black & White (including Black II & White II). You can obtain darmanitan after completing the main story by going to the desert resort and speaking to Professor Juniper, who gives you a RageCandyBar. This allows you to wake up one of the Darmanitans. However, it's probably easier to evolve one from Duramaka. It evolves at level 35.
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You can use the RageCandyBar in the Desert Resortto awaken Darmanitan in Pokemon Black and White.
Darmanitan can`t evolve.It is the last Pokemon in the evolution chain.It has a pre-evolved form which is Darumaka.
Zen Mode is not an evolution, it is an ability that some Darmanitan have. They change to Zen Mode in battle when their HP is low. To get a Darmanitan that can do this, you need to get a Darumaka from the Global Link website, and evolve it to Darmanitan. Also, you can use a rage candy bar ( you get it in winter in the ice town ) at the statues outside the desert resort. These Darmanitan have the Zen Mode ability.
Darumaka evolves into Darmanitan at level 35.
Darumaka evolves into Darmanitan at level 35.