If you are playing the main Pokemon games, you will need to teach one of your Pokemon the TM/HM Rock Smash. (In Pokemon XY it is considered a TM) In Pokemon Ranger: Shadows of Almia it is taught at the beginning of the game that you will need a Pokemon that have the ability to crush rocks. Bidoof is one of the beginning Pokemon as an example.
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make sure a Pokemon in your party knows the move Rock Smash.walk up to the rock you want to smash and press the "A" button
You have to find the (hm) strength make a pokemon learn it then when you click on a rock you will be able to push it I dont know where to find strength as I have never played leaf green but I know how to use strength
You need the move rock smash and you need to beat the oreburge or this gym i forgot what it is to use it outside of battle. If its not oreburge gym then email me at rachel-le123@hotmail.com and it needs the -
You can catch it at the Safari Zone in Fuschia City but it is rare. Throw rocks at it and make sure it doesn't flee so you can catch it easier.
In video games, the only version you can make your Pokemon follow you is in Pokemon yellow ( only pikachu), Pokemon heartgold, and Pokemon soulsilver