On route 13 in one of the houses there is a move tutor that can have your evolved form of a starter learn frenzy plant, blast burn or hydro cannon depending on the type
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Im pretty sure its Frenzy plant. Only Venusaur, Meganium, Sceptile, Torterra, and Serperior can learn it.
You can't teach a Roselia Solarbeam without using a TM and only finally evolved starter grass Pokemon can learn Frenzy Plant.
In Pokémon Black, the moves that Serperior is capable of learning via level up are ones such as Leer, Tackle, Wrap, Vine Whip, Leech Seed, Growth, Leaf Tornado, Slam, Mega Drain, Leaf Blade, Giga Drain, Coil, Gastro Acid, Wring Out and Leaf Storm.
on route 228 there is a house talk to a man he let torterra learn frenzy plant ,same 4 infernape but he learn blast burn again with empoleon i think he learn hydro pump
I believe you go to the Move Tutor in Blackthorn City.