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in heartgold master ball.in soulsilver bring a water Pokemon and use a water type move on it.then use a ultra ball.bring lots of ultra balls and dusk balls.
In Pokémon HeartGold and SoulSilver, the PokéBalls that you can get are: Poké Balls, Heal Balls, Great Balls, Net Balls, Dusk Balls, Friend Balls, Level Balls, Moon Balls, Heavy Balls, Lure Balls, Fast Balls, Luxury Balls, Ultra Balls, Love Balls, Nest Balls, Premier Balls, Quick Balls, Repeat Balls, Safari Balls, Timer Balls and Master Balls.
i would suggest dusk and ultra balls but if you want to capture it without lowering its hp get a friends lugia and use repeat balls
Mantine are quite uncommon but appear on the sea-route between the Whirl Islands and Cianwood. I would take a few ultra balls and dive balls, as these dont like to be caught
you can't buy ultra balls until you beat the 5th gym