First go to mt pyre get the magma emblem then go up jagged pass on the acro bike. the floor will start to vibrate and the cve will appear
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you can catch one in team magmas hideout
after getting into team magmas hideout
team magmas hideout is where you go down from the cable car, east of lavaridge. aqua is a surf north away from lilycove or mossdeep, i forgot sorry.
Go to lilycove city and surf right then up into a cave by the sea. Then go through the door that is above the room.
There is a master ball in the Team Magma's hideout in Pokémon Ruby Sapphire, and Emerald. Look in the Hoenn region for the Team Magma's base of operations.