You can get surf in Pokemon Black and White by battling Cheren at the Twisted Mountain. Then Champion Alder will give both you can Cheren th HM Surf.
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there is no defog in pokemon black/white
Rollout isn't a TM.
Get a Pokemon with surf. then go to the bridge in between Floaroma Town and Valley windworks. Surf to the right of the bridge. There will be an electrizer and a thunderbolt TM.
u can't get it it is not a tm
I don't believe there is a TM for Agility. :(