i think you have to migrate it from Pokemon fire red,leaf green,Pokemon emerald and so on and on and on lol
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poliwhirl has to be traded with a kings rock to get politoed
No, you can only do that by trading, not migrating.
slowpoke to slowking poliwhirl to politoed
Trade the poliwhirl while it holds the item King's Rock then ask for the politoed back from the person you traded it to.
Take a leaf stone and use it on him.