Breed in the daycare with ditto
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once you meet bill in goldenrod city he gives you a eevee.You can't catch Eevee. You receive Eevee from Bill in Goldenrod City. If you want to have more than one Eevee so you can get all the evolutions, put an Eevee and a Ditto in the daycare. They will have an egg and it will be an Eevee. Also you can get one from the prize corner in celadon city for 6,666 pointsTo find eevee in heartgold or soulsilver, you can go to bill's house in goldenrod city, which is on the left side of the Pokemon center where the hosues are, and when you talk to him. He will give you a eevee but remember to have a space in your party or you won't be able to get it until you do.
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To get more than 1 Eevee on Pokemon platinum you can migrate some from a Pokemon GBA game OR get a Ditto and breed it with your Eevee. The final way is to use an action replay/gameshark to find some more. The codes for an action replay can be found at www.codejunkies.com
go to youtube.com and type in your ?. it`ll help more than this.
Breed eevee with a ditto. This works for both male and female eevees, although if you are lucky enough to own a female eevee then there are other Pokemon you can breed it with. Check http://www.serebii.net/pokedex-dp/133.shtml for a list