You must breed evee or an evolution of it at the breeding place on four island.
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Breed in the daycare with ditto
To get more than 1 Eevee on Pokemon platinum you can migrate some from a Pokemon GBA game OR get a Ditto and breed it with your Eevee. The final way is to use an action replay/gameshark to find some more. The codes for an action replay can be found at www.codejunkies.com
Please note Eevee and Gloom can evolve through use of more than 1 stone. Listed only relates to the cateogory this is in, there are many other Pokemon in later generations. Thunder: Pikachu Eevee Moon: Nidorina Nidorino Clefairy Fire Vulpix Growlithe Jigglypuff Eevee Grass: Gloom Weepinbell Exeggcute Sun: Gloom Water: Poliwhirl Eevee Staryu Shellder
Breed eevee with a ditto. This works for both male and female eevees, although if you are lucky enough to own a female eevee then there are other Pokemon you can breed it with. Check http://www.serebii.net/pokedex-dp/133.shtml for a list
yes, it is a mansion Pokemon well you can also breed it at the daycare with a ditto, then hatch the egg