You can either catch the Pokemon, use the move thief on a pikachu that has one, but make sure that Pokemon isn't holding anything, or else it will fail. I think that the move trick switchs items that the Pokemon is holding, and your Pokemon does not need to be holding an item. However, only like 10% of the pikachus you battle will be holding the said item, so in other words, it is rare. To tell the truth, I don't know if 10% is the right percentage, but I know it is low, so look forward to a long time of stealing items from pikachu, most of them are holding berries. On the plus side, you'll get alot of berries.
The easiest way to get a light ball is to trade a Pikachu over from then yellow version. When he is traded over he has the light ball in his equipment
there is no easy way well i dont know if the yellow pikachu has but if you want one with light ball there is a 5% to catch it with the item
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pikachu with light ball is better
I do not know it but you can get it by trading your Pikachu from Generation 1 (Yellow). It is sure to have a Light Ball. My estimation is 5% by using 'Thief' on wild Pikachus.
First, u find a pikachu that has the item, "Light Ball", which is very hard to find, but eventually u will. (or if u have hgss, red's pikachu is holding a light ball. You can use thief or trick to take it from him) Then find a girl Pikachu and someone who can breed with it. Have the male hold the Light Ball and when the baby Pichu hatches it will have Volt Tackle. Hope this helps!
i have pokemon emerald and when i caught a wild pikachu in the safari zone it was holding a light ball and i breeded with a ditto and got a pichu with volt tackle so just catch a pikachu and keep trying ultil it is holding one
There is only one sure-fire way to evolve a pikachu into raichu. The way to do it is by using a thunderstone on Pikachu. If you breed pikachu while it is holding a light ball, you can even get a Pichu.