Grouvyle will learn leaf blade at lvl 29.
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You can't catch a poliwag in Pokemon Sapphire. You have to trade from Pokemon Fire Red or Pokemon Leaf Green.
behind the door is leaf green u enter the Pokemon leaf green world
you can not catch scyther in Pokemon ruby,emerald or sapphire . you have to trade them from Pokemon fire red or leaf green.
As far as I Know Chansey is not on the Pokemon Sapphire you can trade it from other versions like fire red or leaf green
go underground and look for them