in order to get heat wave first get a charlizard by going to the move tutor in Firered/ Leafgreen. But in Emerald Charkoal learns it at lvl 48.
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In the heat gym
The TM thunder wave no longer is a TM.
You have to get it in a trade.
sorry, you can't get riolu in Pokemon emerald version.
No you cannot catch Entei in Pokemon Emerald.