First, go to Ecruteak city and find the Burned Tower. Once inside, all three dogs ; Entei,Raikou,Suicune will run away from you when you enter the bottom floor, they will be roaming Johto and Kanto, when you find it , lower it's hp down to either 1,2,3,4,5. USE MEAN LOOK OR BLOCK FIRST other wise it will flee, after 5 or lower hp now use hypnosis: only because it doesn't faint it , only make it sleep, use at least 1-7 ultra balls because they're most effective other then master ball which is a real waste
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i am fairly sure you can't.
It means you have not seen it, but if you have you should also see Entei n the map, if you see Entei but not Raikou it means that Raikou is currently on the same route as you.
you cant catch entei on Pokemon pearl. entei is a johto Pokemon and Pokemon pearl is a sinnoh game. the only way to getentei is to trade it over from another game games compatible are Pokemon diamond, Pokemon platinum, Pokemon soulsilver and Pokemon heartgold. the last two i am sure you can get entei. (i have seen it in the wild)
after that, someone at the battle frontier will tell you about latias and latios. then, latias will start roaming kanto.
It doesn't. Flare Blitz is a move only fire-type starter Pokemon can learn.