You can only get a Shiftry by evolving a Seedot twice.
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Shiftry cannot be found in Pokémon Emerald however you can catch wild Seedot in Routes 102, 117 and 120 and then you can evolve it into Nuzleaf once it reaches Level 14 and then you can use a Leaf Stone on Nuzleaf in order to evolve it into Shiftry and you can find Nuzleaf in Routte 114 and then you can use a Leaf Stone in order to evolve it into Shiftry additionally you can make a trade with a trainer in order to receive Seedot, Nuzleaf or Shiftry via trade.
it depends on what moves you them. vileplume can beat shiftry in one hit of sludge bomb and shiftry can beat vilaplume with explosion (from seedot).
Faint attack Giga Drain Sandstorm Teeter Dance/Leech Seed/Toxic/Double Team Between a Cacturne and a Shiftry, Cacturne has higher offense, while Shiftry has higher HP and speed: Shiftry: 90 HP, 100 Attack, 60 Defense, 90 Sp. Atk, 60 Sp.Def, 80 Speed. Cacturne: 70 HP, 115 Attack, 60 Defense, 115 Sp.Atk, 60 Sp.Def, 55 Speed.
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